Lanthanide molecular oxohydroxides: Synthesis and characterisation of [Y4(μ4-O)(μ-OEt)2(μ,η2-AAA)2(η2-AAA)3]2(μ3-OH)4(μ3-OEt)2 (HAAA = allylacetatoacetate)期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Lanthanide molecular oxohydroxides: Synthesis and characterisation of [Y4(μ4-O)(μ-OEt)2(μ,η2-AAA)2(η2-AAA)3]2(μ3-OH)4(μ3-OEt)2 (HAAA = allylacetatoacetate)

Affiliation:	1. Sci. Mat. Lab., Fac. Ciencias Químicas, Universidad Autónoma de Puebla, P.O. Box 1067, 72001 Puebla, Mexico;2. Posgrado en Optoelectrónica Fac. Ciencias Fisicomatemáticas, Universidad Autónoma de Puebla, Mexico;3. Centro de Vinculación Universitaria, Puebla, Mexico

Abstract:	The reaction between Y₅O(OPrⁱ)₁₃ and allylacetatoacetate or 2-(methacryloyloxy)ethyl acetatoacetate in 1:5 stoichiometry afforded octanuclear oxohydroxo species. Structural characterization was achieved for the allylacetatoacetate derivative homo and copolymerisation reactions with styrene were evaluated for doping of polystyrene. Hydoxo species, Y₄(OH)₂(AAA)₁₀, where also obtained by reacting Y[N(SiMe₃)]₃ and HAAA.

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