A first mixed heteropentametallic transition metal complex: Synthesis and characterisation |
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| Affiliation: | 1. College of Chemical Engineering, Guizhou University of Engineering Science, Bijie 551700, China;2. Guizhou Province New Coal-based Materials Engineering Center, Bijie 551700, China;1. Institute of Physical and Organic Chemistry, Southern Federal University, Stachki Ave. 194/2, 344090, Rostov-on-Don, Russian Federation;2. Institute of Problems of Chemical Physics of Russian Academy of Sciences, Akad. Semjonov N.N. Ave. 1, 142432, Chernogolovka, Moscow Region, Russian Federation;1. G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, 49 Tropinina Str., 603950 Nizhny Novgorod, Russia;2. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a Institutskaya Str., 630090 Novosibirsk, Russia;3. Research Institute of Physics, Southern Federal University, 194 Stachka Ave., 344090 Rostov-on-Don, Russia |
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| Abstract: | The synthesis and characterisation of a novel (η2-dppf)(η5-C5H5)Ru(C C)-1,4-(C6H4)PPh2–Au–CC-bipy({Ti](μ-σ,π-CCSiMe3)2}Cu)]PF6 (dppf = 1,1′-bis(diphenylphosphino)ferrocene) is reported in which five different transition metals (Fe–Ru–Au–Cu–Ti) are linked by carbon-rich organic bridging units. |
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