Solvothermal synthesis,crystal structure and photoluminescent property of a novel 3D cadmium(II) coordination polymer containing [Cd5(μ3-OH)2(μ3-OAc)2]6+ cores |
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| Affiliation: | 1. College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, PR China;2. Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun 130024, PR China;1. Chemical Engineering Department, National Taiwan University of Science and Technology, Taipei 106-07, Taiwan;2. Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia |
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| Abstract: | A novel 3D coordination polymer, {[Cd5(μ3-OAc)2(μ2-OAc)2(μ3- OH)2(pam)2(4,4′-bpy)2] · CH3CH2OH}n (1) (H2pam = pamoic acid, HOAc = acetic acid, 4,4′-bpy = 4,4′-bipyridyl), was solvothermally synthesized and characterized by the single crystal X-ray diffraction. The title compound contains unprecedented [Cd5(μ3-OH)2(μ3-OAc)2]6+ pentanuclear building units which are linked through pam and 4,4′-bpy ligands to afford a three-dimensional structure. The infrared spectroscopy, thermal stability and photoluminescence of the complex were studied. |
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