The novel polymeric potassium complex with a new coordination mode of orotic acid [K(μ5-H2Or)(μ-H2O)]n: Synthesis and structural characterization |
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| Affiliation: | 1. Department of Chemistry, Faculty of Arts and Sciences, Eski?ehir Osmangazi University, 26480 Eski?ehir, Turkey;2. Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139 Kurupelit, Samsun, Turkey;1. Department of Bioorganic Chemistry, Institute of Chemistry and Food Technology, Faculty of Engineering and Economics, University of Economics, 180/120 Komandorska, 54-435 Wroc?aw, Poland;2. Laboratoire de Photonique Quantique et Moleculaire, Institut d‘Alembert, Ecole Normal Superieure de Cachan, 61 av. du President Wilson, 94235 Cachan, France;3. Faculty of Chemistry, University of Wroc?aw, 14 F. Joliot-Curie, 50-383 Wroc?aw, Poland;1. Department of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, PR China;2. School of Life Sciences, Shandong University of Technology, Zibo 255049, PR China;1. Departamento de Química Inorgánica, Universidad de Granada, 18071 Granada, Spain;2. Departamento de Química Inorgánica y Analítica, Universidad Rey Juan Carlos, Móstoles, Madrid, Spain;3. Departamento de Química Aplicada, Facultad de Ciencias Químicas de San Sebastián, Universidad del País Vasco UPV/EHU, 20018 San Sebastián, Spain;4. Departamento de Química Analítica, Universidad de Granada18071, Granada, Spain |
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| Abstract: | Novel polynuclear seven-coordinated potassium complex, K(μ5-H2Or)(μ-H2O)]n(H3Or = orotic acid), with the new coordination mode of orotic acid has been prepared and characterized by elemental analysis, FT-IR spectra, X-ray diffraction. The orotate ligand exhibits new coordination mode of μ5-κO, O: κO′, O′: O″ for H2Or?. |
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