Synthesis and characterization of half-sandwich Ir and Ru complexes containing Mnt ligand (Mnt = maleonitriledithiolate) |
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| Affiliation: | 1. Department of Chemistry, Faculty of Science, University of Zanjan, 45371-38791 Zanjan, Iran;2. Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, Wroclaw 50-383, Poland;3. Departamento de Química Inorgánica I, Universidad Complutense, 28040 Madrid, Spain;1. Fakulteta za kemijo in kemijsko tehnologijo, Univerza v Ljubljani, Aškerčeva c. 5, 1000 Ljubljana, Slovenia;2. Ruđer Bošković Institute, Zagreb, Croatia;3. Institut des Matériaux Jean Rouxel, Université de Nantes, Cedex 3, France;4. Leiden Institute of Chemistry, Leiden University, Leiden, The Netherlands;5. Department of Chemistry, King Saud University, Riyadh, Saudi Arabia;1. Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Kojirakawa, Yamagata 990-8560, Japan;2. Department of Chemistry, Biology and Marine Science, Faculty of Science, University of the Ryukyus, Nishihara, Nakagami-gun, Okinawa 903-0213, Japan;3. Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo 1, Saga 840-8502, Japan;1. School of Science and Engineering, Meisei University, 2-1-1 Hodokubo, Hino, Tokyo 191-8506, Japan;2. Faculty of Science Division I, Department of Chemistry, Tokyo University of Science, Kagurazqaka 1-3, Shinjyuku-ku, Tokyo 162-8601, Japan |
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| Abstract: | The reaction of [Cp1IrCl2]2 and [(p-Cymene)RuCl2]2 with disodium maleonitriledithiolate (Na2Mnt) yield the 16-electron complexes Cp1Ir(Mnt) (1) and [(p-Cymene)Ru(Mnt)] (2). Complexes 1 and 2 can further react with PPh3 to form the corresponding 18-electron complexes Cp1Ir(Mnt)PPh3 (3) and [(p-Cymene)Ru(Mnt)PPh3] (4). All complexes have been fully characterized by IR and NMR spectroscopy, as well as elemental analysis. The molecular structures of 1 and 4 have been confirmed by X-ray crystallography. |
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