Two Mn(II)–Au(I) supramolecular assemblies bonded by coordination,aurophilicity and hydrogen-bonding, π–π interactions and their magnetic properties |
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| Affiliation: | 1. Instrumental Analysis and Research Center, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, PR China;2. Department of Chemistry, College of Sciences, Shanghai University, Shanghai 200444, PR China |
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| Abstract: | Two Mn(II)–Au(I) supramolecular assemblies {{MnAu(CN)2]2(H2O)4} Au(CN)2]2(H2bpy) · H2O}(bpy = 4,4′-bipyridine) 1 and {Mn(4,4′-dmbpy) Au(CN)2]2(CH3OH)} (4,4′-dmbpy = 4,4′-dimethyl-bipyridine) 2 have been synthesized and magnetic properties have been investigated The interplay of aurophilicity, coordination, hydrogen-bonding and π–π interactions in two complexes result in three-dimensional network. |
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