Synthesis,crystal structure and luminescence of novel two-dimensional interpenetrating frameworks |
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Affiliation: | 1. College of Chemistry and Materials Engineering, Guiyang University, Guiyang 550005, PR China;2. School of Chemistry and Environmental Science, Guizhou Minzu University, Huaxi University Town, Guiyang 550025, PR China |
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Abstract: | Two novel metal coordination polymers, Zn(nic)(isonic)]n (1) and Cu(nic)(isonic)]n (2) (H2nic = nicotinic acid, H2isonic = isonicotinic acid), have been hydrothermally synthesized and characterized by elemental analysis, IR, and single crystal X-ray diffraction. X-ray single-crystal structural analyses reveal that 1 and 2 are isomorphous, two-dimensional interpenetrating (4, 4) frameworks bridged by nic and isonic ligands, and further assembled into a three-dimensional supramolecular structure via π–π stacking interaction. Moreover, 1 displayed photoluminescent properties in the blue range at room temperature. |
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