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An organic–inorganic hybrid uranyl nicotinate molybdate polymer and its fluorescent property
Affiliation:1. National Engineering Research Centre of Industrial Crystallization Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;2. College of Chemical Engineering, North China University of Science and Technology, Tangshan 063210, China;3. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China;1. State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001, China;2. School of Materials Science and Engineering, Harbin Institute of Technology, Harbin, China;3. School of Chemistry and Chemical Engineering, MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, Harbin Institute of Technology, Harbin 150001, China;1. Cardiovascular Center, Department of Internal Medicine, University of Michigan Medical Center, NCRC Bldg 26, Rm 361S, 2800 Plymouth Road, Ann Arbor, MI 48109, USA;2. Department of Cancer Biology, University of Cincinnati College of Medicine, Vontz Center, 3125 Eden Avenue, Cincinnati, OH45267, USA;3. Department of Computational Medicine and Bioinformatics, University of Michigan, Ann Arbor, MI48109, USA;4. Department of Pathology and Translational Pathobiology, Louisiana State University Health Sciences Center-Shreveport, Shreveport, LA71103, USA;5. Wellcome Centre for Human Genetics, University of Oxford, Oxford, UK;6. Department of Medicinal Chemistry and Molecular Pharmacology, College of Pharmacy, Purdue University, West Lafayette, IN, USA;7. Center for Molecular Medicine and Genetics, Wayne State University School of Medicine, Detroit, MI48201, USA;8. Department of Genetics, University of Pennsylvania, Philadelphia, PA, USA;9. Department of Biostatistics, University of Michigan School of Public Health, Ann Arbor, MI, USA;10. K.G. Jebsen Center for Genetic Epidemiology, Department of Public Health and Nursing, Faculty of Medicine and Health Sciences, Norwegian University of Science and Technology, NTNU, Trondheim, Norway;11. Department of Pharmaceutical Sciences, Eugene Applebaum College of Pharmacy and Health Sciences, Wayne State University, Detroit, MI 48201, USA;12. Department of Human Genetics, University of Michigan, Ann Arbor, MI, USA;1. Materials Science and Engineering Postgraduate Program – PPGCEM, Federal University of Rio Grande Do Norte – UFRN, Natal, 59078-970, Brazil;2. Centre for Mechanical Technology and Automation – TEMA, Mechanical Engineering Department, University of Aveiro, Aveiro, 3810-193, Portugal;3. Department of Materials and Ceramic Engineering, CICECO – Aveiro Institute of Materials, University of Aveiro, Aveiro, 3810-193, Portugal;4. Materials Science and Engineering Postgraduate Program – PPCEM, Federal University of Paraíba – UFPB, João Pessoa, 58051-900, Brazil;1. Key Laboratory of Low-grade Energy Utilization Technologies and Systems, Chongqing University, Ministry of Education, Chongqing, 400030, PR China;2. School of Energy and Power Engineering, Chongqing University, Chongqing, 400030, PR China
Abstract:A uranyl nicotinate molybdate polymer UO2(nicot)(MoO3OH)]n (Hnicot = nicotinic acid, NC5H4CO2H) was synthesized by the hydrothermal reaction of uranyl nitrate UO2(NO3)2 · 6H2O], phosphomolybolic acid (H3PMo12O40) and nicotinic acid. Its crystal structure and fluorescent property were measured. The results show that the crystal packs in the 1D chains of uranyl molybdates with strong fluorescence at the range of 470–520 nm.
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