Linked macrocyclic systems. Interaction of copper(I) with tris-ring N2S2-donor macrocycles and their single-ring analogues期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Linked macrocyclic systems. Interaction of copper(I) with tris-ring N2S2-donor macrocycles and their single-ring analogues

Affiliation:	1. Rutgers University, Department of Materials Science and Engineering, Piscataway, NJ, 08854, USA;2. Argonne National Laboratory, Advanced Photon Source, Lemont, IL, 60439, USA

Abstract:	The interaction of two tri-linked N₂S₂-donor macrocyclic ligands, 1 (R = H) and 2 (R = H), and their related single ring derivatives, 3 (R = H) and 4 (R = CH₂C₆H₅), with copper(I) is reported. Solid 3:1 (metal:ligand) complexes of type Cu₃L](PF₆)₃ (L = 1 and 2, R = H) and single ring derivatives of type CuL]PF₆ (L = 3, R = H; L = 4, R = CH₂C₆H₅) were isolated; the X-ray structure of CuL]PF₆ (L = 3, R = H) showed that the four macrocyclic donor atoms coordinate to the copper(I) in a quasi-tetrahedral manner (Cu–N 2.089, 2.096(4); Cu–S 2.239, 2.264(2) Å, X–Cu–Y 104.5(1)–115.4(1))°.

Keywords:
本文献已被 ScienceDirect 等数据库收录！