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直流磁控溅射沉积WO3薄膜电致变色性能研究
引用本文:何延春,邱家稳. 直流磁控溅射沉积WO3薄膜电致变色性能研究[J]. 真空与低温, 2007, 13(1): 16-20
作者姓名:何延春  邱家稳
作者单位:兰州物理研究所,表面工程技术国家级重点实验室,甘肃,兰州,730000
摘    要:以金属钨为靶材,采用直流反应磁控溅射方法,在玻璃上制备电致变色WO3薄膜.利用X射线衍射(XRD)方法对薄膜的结构进行了分析,得出了WO3薄膜的沉积工艺.制备了WO3/TTO/Glass电致变色器件,并对其性能进行了研究.结果表明在Li+注入前后,薄膜的透射率平均变化约50%,具有较好的可逆变色特性;Li+注入后,WO3薄膜中的一部分W6+变为W5+,转化比例约为25%.

关 键 词:直流磁控溅射  电致变色  薄膜
文章编号:1006-7086(2007)01-0016-05
修稿时间:2007-01-15

THE ELECTROCHROMIC PROPERTIES OF WO3 THIN FILMS BY DC MAGNETRON SPUTTERING
HE Yan-chun,QIU Jia-wen. THE ELECTROCHROMIC PROPERTIES OF WO3 THIN FILMS BY DC MAGNETRON SPUTTERING[J]. Vacuum and Cryogenics, 2007, 13(1): 16-20
Authors:HE Yan-chun  QIU Jia-wen
Abstract:Using pure tungsten as target,WO3 thin films were prepared on glass substrate by DC reactive magnetron sputtering.Its crystal structures were analyzed by X-ray diffraction(XRD) method.The deposition technology of the WO3 thin film was obtained.Electrochromism device of WO3/ITO/Glass was prepared and its properties were studied.The experimental results showed that the transmissivity of the WO3 thin film changed about 50% after the Li ions in jection.The device has a preferably reversible electrochromism performance,about 25% of W6+ in the WO3 thin film change to W5+.
Keywords:WO3
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