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Strengthening and toughening of thermoplastic polyolefin elastomer using polypropylene‐grafted multiwalled carbon nanotubes
Authors:Chaoqun Li  Hua Deng  Ke Wang  Qin Zhang  Feng Chen  Qiang Fu
Affiliation:College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China
Abstract:In this article, it is demonstrated that simultaneously strengthened and toughened nanocomposites based on polypropylene/EPDM thermoplastic elastomer (TPO) matrix can be achieved through enhanced adhesion between MWNTs and polymer matrix by using PP grafted multiwalled carbon nanotubes (MWNTs). To improve the interface between filler and matrix, MWNTs were treated with acid, or covalently linked to polypropylene. The chemical and morphological transformation of the modified MWNTs, and its effect on the morphology and mechanical properties of the composites are investigated. The strengthening and toughening mechanism is discussed regarding the structural property relationship. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011
Keywords:thermoplastic polyolefin  carbon nanotubes  strengthening and toughening
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