Fabrication and absorption intensity analyses of Er2O3 nanoparticles suspended in polymethyl methacrylate

Nanoparticles suspended in polymeric host materials are found to have tremendous potential for various photonic and biological applications due to their unique material properties. Polymethyl methacrylate (PMMA) is known to be one of the best vinyl polymers owing to its excellent dimensional quality, weather resistance, easiness of synthesis, resistance to laser damage, and high mechanical strength. In this article, we describe a methodology to fabricate thin discs of nanocrystalline erbium oxide (Er₂O₃) suspended in PMMA (Er₂O₃/PMMA). The optical transparency of PMMA was confirmed in the ultraviolet, visible, and the near‐infrared regions of the electromagnetic spectrum, making it possible to observe only the Er₂O₃ spectra over the wavelength investigated. The room‐temperature absorption spectrum of Er₂O₃/PMMA has been taken in the 400 to 820 nm wavelength region. Analysis of the spectrum reveals a consistent agreement between our experimental data and those reported earlier for Er³⁺ in nanocrystalline Er³⁺ : Y₂O₃. A solid solution exists between Er₂O₃ and Er³⁺ : Y₂O₃ in terms of their physical properties. Therefore, our experimental results conclude that the presence of PMMA does not significantly alter the crystal symmetry as well as the co‐ordination environment of the Er³⁺ ions in Er₂O₃. Our results also emphasize that the Er₂O₃/PMMA may have future possibilities for numerous technological applications. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011