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Nanoscale synthesis and optical features of metallic nickel nanoparticles by wet chemical approaches
Authors:Khalid Nouneh  Munetaka OyamaRaquel Diaz  Mohammed Abd-LefdilIV Kityk  Mosto Bousmina
Affiliation:a INANOTECH, Institute of Nanomaterials and Nanotechnology, MAScIR Moroccan Advanced Science, Innovation and Research Foundation, ENSET, Av. Armée Royale, Rabat, Morocco
b Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8520, Japan
c Department of Física Aplicada C-XII, Universidad Autónoma de Madrid, Madrid, Spain
d Laboratory of Materials Physics, University Mohammed V, Rabat, Morocco
e Electrical Engineering Department, Czestochowa University of Technology, Armii Krajowej 17, Czestochowa, Poland
f Hassan II Academy of Science and Technology, Rabat, Morocco
Abstract:Nickel nanoparticles (Ni-NPs) were successfully synthesized and attached on indium tin oxide (ITO) substrate by two different methods: from solution reduction process by using sodium borohydride (NaBH4) as reducing agent in the presence of poly(N-vinilpyrrolidone) (PVP) as protective and stabilizing agents and by polyol process under ethylene glycol EG as a solvent. The results indicated that the samples prepared in aqueous solution show the occurrence of face-centered cubic metallic nickel nanoparticles with a medium diameter of ∼31 nm and good size dispersion compared to the preparation in EG that revealed large size ∼150 nm. The dynamics of the nanoparticle's growth in the solvents and comparison with optical absorption is presented.
Keywords:Nickel nanoparticles  Wet chemical  Surface modification  Nanostructured material  SPR  Indium tin oxide
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