Preparation and characterization of novel nanocomposites based on polyacrylonitrile/kaolinite |
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Authors: | Dewen Sun Yanfeng LiBo Zhang Xiaobing Pan |
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Affiliation: | State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Institute of Biochemical Engineering & Environmental Technology, Lanzhou University, Lanzhou 730000, China |
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Abstract: | A novel intercalation nanocomposite based on polyacrylonitrile (PAN)/kaolinite was prepared by a simple in situ emulsion polymerization in the presence of organically modified layered silicates (kaolinite). The crude kaolinite (K0) was firstly modified by dimethylsulfoxide-methanol and potassium acetate-aqueous systems; acrylonitrile monomer was then intercalated into kaolinite by displacing potassium acetate from KAc-kaolinite (the kaolinite modified by KAc, marked as K2). The polymer/kaolinite composites were prepared by in situ emulsion polymerization, and characterized by means of X-ray diffraction, scanning electron microscope, transmission electron microscope and thermal gravimetric analysis. Experimental results indicate that the clay layers of kaolinite in PAN/K2 composites are well distributed and delaminated. The weight-average molecular weights were measured by small-angle X-ray scattering for all samples. The presence of clay results in an increase in molecular weights compared to pure PAN polymer due to the highly crosslinked structure. |
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Keywords: | A Polymer&ndash matrix composites A Layered structures A Nanoclays B Thermal properties D Scanning/transmission electron microscopy (STEM) |
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