Improvement of anticorrosive performance of phosphate-based alkyd paints with suitable additives |
| |
Authors: | G Blustein M C Dey?? R Romagnoli A R Di Sarli B del Amo |
| |
Affiliation: | (1) CIDEPINT, Centro de Investigaci?n y Desarrollo en Tecnolog?a de Pinturas (CICPBA-CONICET), Calle 52 e/121 y 122, B1900AYB La Plata, Argentina |
| |
Abstract: | The purpose of this investigation was focused on reducing the content of zinc phosphate in anticorrosive paints by means of
the incorporation of low quantities of selected soluble corrosion inhibitors. The article describes the anticorrosive behavior
of alkyd paints containing reduced levels of zinc phosphate, zinc oxide, and some soluble compounds used as additives (e.g.,
sodium polyphosphate, sodium phosphate, and sodium benzoate). Anticorrosive solventborne alkyd paints were formulated with
a zinc phosphate content of 10% by volume (v/v) with respect to the total pigment concentration. In all cases, the PVC/CPVC
(pigment volume concentration/critical pigment volume concentration) ratio was 0.8. Experimental paints, applied on sandblasted
SAE 1010 panels, were evaluated by accelerated tests (salt spray cabinet) and electrochemical measurements (electrochemical
impedance spectroscopy, EIS). The results show that the additions of small amounts of soluble corrosion inhibitors to low
content zinc phosphate paint formulations enhance their performance in a very remarkable way. Perhaps, the most outstanding
feature is that the employment of soluble additives allowed the reduction of the zinc phosphate content with concomitant savings. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|