| 聚醚-酯嵌段共聚物提高聚氨酯弹性体水解稳定性的研究 |
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| 引用本文： | 殷宁,亢茂青,冯月兰,封悦霞,王心葵.聚醚-酯嵌段共聚物提高聚氨酯弹性体水解稳定性的研究[J].高分子材料科学与工程,2007,23(4):105-109. |
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| 作者姓名： | 殷宁 亢茂青 冯月兰 封悦霞 王心葵 |
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| 作者单位： | 中国科学院山西煤炭化学研究所,山西,太原,030001 |
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| 摘 要： | 采用双金属络合催化剂(DMC),以脂肪族己二酸系聚酯多元醇为起始剂,与环氧丙烷、环氧乙烷进行烷氧基化反应,制得聚醚酯多元醇用于聚氨酯弹性体(PUE)的合成,可得到综合性能优良的PUE材料。在相同硬段含量下,聚醚酯型PUE的力学性能接近纯聚酯型PUE,优于纯聚醚型PUE,并且其耐水解性能得到较大的提高,接近纯聚醚型PUE。
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| 关 键 词： | 双金属络合催化剂 烷氧基化反应 聚醚酯多元醇 聚氨酯弹性体 水解稳定性 力学性能 |
| 文章编号： | 1000-7555（2007）04-0105-05 |
| 修稿时间： | 2006-05-15 |
Study on Developing Hydrolysis Stability of Polyurethane Elastomer Modified by Poly(Ether-Ester) Segmented Copolyols |
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| YIN Ning,KANG Mao-qing,FENG Yue-lan,FENG Yue-xia,WANG Xin-kui.Study on Developing Hydrolysis Stability of Polyurethane Elastomer Modified by Poly(Ether-Ester) Segmented Copolyols[J].Polymer Materials Science & Engineering,2007,23(4):105-109. |
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| Authors: | YIN Ning KANG Mao-qing FENG Yue-lan FENG Yue-xia WANG Xin-kui |
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| Affiliation: | Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China |
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| Abstract: | Polyesterether polyols were prepared by the alkoxylation reaction of polyester polyols with propylene oxide initiator in the presence of DMC catalyst.The polyurethane elastomers made using mentioned above polyetherester polyols exhibit excellent comprehensive performances.Under the same hard segment content,the mechanical properties of the polyurethane elastomers are much better than of polyether based elastomer,approaching the level of polyester based ones while hydrolytic stability gains obvious enhancement,compared with polyester type elastomers. |
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| Keywords: | double-metal cyanide catalyst alkoxylation polyetherester polyols polyurethane elastomer hydrolysis stability mechanical properties |
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