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呋喃树脂改性煤沥青的机理及热行为研究
引用本文:杨琴,李铁虎,王娟,江元汝.呋喃树脂改性煤沥青的机理及热行为研究[J].煤炭转化,2006,29(1):66-68,72.
作者姓名:杨琴  李铁虎  王娟  江元汝
作者单位:1. 西北工业大学材料科学与工程学院,710072,西安
2. 西安建筑科技大学,710055,西安
摘    要:以呋喃树脂为改性剂对煤沥青进行了改性,采用傅立叶红外光谱(FT-IR)和扫描电镜(SEM)对呋喃树脂改性煤沥青的机理进行了分析;采用热重和示差扫描量热技术(TG-DSC)对改性前后煤沥青的热解行为进行了分析.实验结果表明,呋喃树脂在煤沥青中起增塑作用,其增塑过程通过四步完成,呋喃树脂与煤沥青发生增塑作用时需要吸收热量;呋喃树脂改性煤沥青的耐热性提高,呋喃树脂对煤沥青的残炭率影响不大.

关 键 词:煤沥青  呋喃树脂  机理  热行为
收稿时间:2005-07-03
修稿时间:2005-07-032005-10-28

STUDY ON MECHANISM AND THERMAL BEHAVIOR OF THE COAL TAR PITCH MODIFIED WITH FURAN RESIN
Yang Qin,Li Tiehu,Wang Juan,Jiang Yuanru.STUDY ON MECHANISM AND THERMAL BEHAVIOR OF THE COAL TAR PITCH MODIFIED WITH FURAN RESIN[J].Coal Conversion,2006,29(1):66-68,72.
Authors:Yang Qin  Li Tiehu  Wang Juan  Jiang Yuanru
Abstract:Modification of coal tar pitch (CTP) as carbon materials was studied using furan resin as a modifer. The modification mechanism was studied using fourier transform infra-red (FT-IR) and scanning electronic microscope (SEM) respectively.Thermal behavior of modified coal tar pitch was analyzed with thermogravimetric and differential scanning calorimetry (TG-DSC).Our experimental findings are the following:1) The furan resin acts as plasticization in the CTP. The plasticization of furan resin in the CTP can be finished through four-part;2) It need absorb heat when plasticization of furan resin in the CTP occurs;3) The thermal stability of the modified coal tar pitch is improved and the influence of furan resin on the carbon yield is quite small.
Keywords:coal tar pitch  furan resin  mechanism  thermal behavior
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