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Synthesis of (Sr,Eu)CO3@SiO2 core-shell-like precursor for alkali earth silicate phosphors
引用本文:胡运生,郝建华,庄卫东,黄小卫,何华强. Synthesis of (Sr,Eu)CO3@SiO2 core-shell-like precursor for alkali earth silicate phosphors[J]. 中国稀土学报(英文版), 2011, 0(10): 911-914
作者姓名:胡运生  郝建华  庄卫东  黄小卫  何华强
作者单位:National Engineering Research Center for Rare Earth Materials;General Research Institute for Nonferrous Metals;and Grirem Advanced Materials Co.;Ltd.;Department of Applied Physics;The Hong Kong Polytechnic University;
基金项目:supported by the National Hi-Tech R&D Program of China (863 Program, 2010AA03A404, 2011AA03A101); Beijing Natural Science Foundation (2102022); the Hong Kong Polytechnic University Grant (J-BB9R)
摘    要:Monodisperse(Sr,Eu)CO3 sphere(the homogenous mixture of Sr2+ and Eu3+ carbonates) was firstly prepared,and then its surfacewas coated by amorphous SiO2 in the presence of cationic surfactant cetyltrimethylammonium bromide(CTAB) to form(Sr,Eu)CO3@SiO2core-shell-like precursor.The overall synthesized mechanism was investigated and proposed based on the Fourier transform infrared spectroscopy(FTIR),X-ray diffraction(XRD) and scanning electron microscopy(SEM).This strategy could be applied to construct core-shellstructured precursors for the preparation of alkali earth silicate phosphors.

关 键 词:core-shell structure  precursor  formation mechanism  phosphor  rare earths

Synthesis of(Sr,Eu)CO_3@SiO_2 core-shell-like precursor for alkali earth silicate phosphors
HU Yunsheng,HAO Jianhua,ZHUANG Weidong,HUANG Xiaowei,HE Huaqiang. Synthesis of(Sr,Eu)CO_3@SiO_2 core-shell-like precursor for alkali earth silicate phosphors[J]. Journal of Rare Earths, 2011, 0(10): 911-914
Authors:HU Yunsheng  HAO Jianhua  ZHUANG Weidong  HUANG Xiaowei  HE Huaqiang
Affiliation:HU Yunsheng1,HAO Jianhua2,ZHUANG Weidong1,HUANG Xiaowei1,HE Huaqiang1(1.National Engineering Research Center for Rare Earth Materials,General Research Institute for Nonferrous Metals,and Grirem Advanced Materials Co.,Ltd.,Beijing100088,China,2.Department of Applied Physics,The Hong Kong Polytechnic University,Hong Kong,China)
Abstract:Monodisperse(Sr,Eu)CO3 sphere(the homogenous mixture of Sr2+ and Eu3+ carbonates) was firstly prepared,and then its surfacewas coated by amorphous SiO2 in the presence of cationic surfactant cetyltrimethylammonium bromide(CTAB) to form(Sr,Eu)CO3@SiO2core-shell-like precursor.The overall synthesized mechanism was investigated and proposed based on the Fourier transform infrared spectroscopy(FTIR),X-ray diffraction(XRD) and scanning electron microscopy(SEM).This strategy could be applied to construct core-she...
Keywords:core-shell structure  precursor  formation mechanism  phosphor  rare earths  
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