| 基于热力学的浸金体系分析 |
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| 引用本文： | 王治科,陈东辉,陈亮.基于热力学的浸金体系分析[J].有色金属(冶炼部分),2006(3):36-38. |
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| 作者姓名： | 王治科 陈东辉 陈亮 |
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| 作者单位： | [1]东华大学环境科学与工程学院,上海200051 [2]河南师范大学化学与环境科学学院,河南省环境污染控制重点实验室,新乡453007 |
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| 摘 要： | 在分析浸金体系基础上,推导浸金过程的热力学判据,提出浸金的平衡常数判据,讨论浸金体系氧化剂和络合剂的关系。浸金体系氧化剂的电位判据和金(Ⅰ/Ⅲ)络合物的稳定常数相关,稳定常数愈大,该浸金体系所需氧化剂的最小氧化电位愈小。
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| 关 键 词： | 金 热力学分析 氧化剂 络合剂 稳定常数 |
| 文章编号： | 1007-7545(2006)03-0036-03 |
The Analysis of Gold Leaching Systems Based on Thermodynamics |
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| WANG Zhi-ke.The Analysis of Gold Leaching Systems Based on Thermodynamics[J].Nonferrous Metals(Extractive Metallurgy),2006(3):36-38. |
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| Authors: | WANG Zhi-ke |
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| Affiliation: | WANG Zhi-ke~ |
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| Abstract: | The thermodynamic and the equilibrium constant criterion of the gold leaching process is deduced and proposed on the basis of analysis of gold leaching systems.The relationship of oxidants and ligands in gold leaching systems is discussed.The gold leaching process with the oxidant may proceed in thermodynamics.The electrical potential criterion of the oxidant in gold leaching systems is related to the stability constant of gold(Ⅰ/Ⅲ) complexes.The stability constant is higher,and the minimum electrical potential needed for the oxidant in the gold leaching systems is lower. |
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| Keywords: | Gold Thermodynamic analysis Oxidants Ligands Stability constant |
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