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新型磺基甜菜碱与聚丙烯酰胺作用的研究
引用本文:丁伟,李金红,曹绪龙,刘坤,潘斌林,于涛,邢欣欣,张微,杨柳.新型磺基甜菜碱与聚丙烯酰胺作用的研究[J].化学工业与工程技术,2013(6):33-35.
作者姓名:丁伟  李金红  曹绪龙  刘坤  潘斌林  于涛  邢欣欣  张微  杨柳
作者单位:[1]东北石油大学化学化工学院石油与天然气化工省重点实验室,黑龙江大庆163318 [2]胜利油田地质科学研究院,山东东营257000
基金项目:国家重大科技专项基金(2011ZX05011-004)资助项目.
摘    要:合成了一种耐温抗盐表面活性剂,通过红外光谱分析了该表面活性剂的结构。将其与2500万分子量聚丙烯酰胺进行复配,考察了复配体系的表面、界面性能。研究结果表明:所合成的产物为目标产物;磺基甜菜碱表面活性剂的临界胶束浓度(cmc)为2.19×10^-3mol/L,临界胶束浓度下的表面张力(γcmc)为25.51mN/m;加入聚合物后临界胶束浓度变为4.09×10^-3mol/L,γcmc变为26.65mN/m;表面活性剂质量浓度在0.8—1.5g/L,可使胜利原油油水间的界面张力达到超低数量级(10^-3mN/m);聚合物的加入有利于乳状液的形成。

关 键 词:甜菜碱表面活性剂  表面张力  界面张力  乳化性能

Research on interaction between novel sulfobetaine and polyacrylamide
DING Wei,LI Jinhong,CAO Xulong,LIU Kun,PAN Binlin,YU Tao,XING Xinxin,ZHANG Wei,YANG Liu.Research on interaction between novel sulfobetaine and polyacrylamide[J].Journal of Chemical Industry & Engineering,2013(6):33-35.
Authors:DING Wei  LI Jinhong  CAO Xulong  LIU Kun  PAN Binlin  YU Tao  XING Xinxin  ZHANG Wei  YANG Liu
Affiliation:1. Provincial Key Laboratory of Oil & Gas Chemical Technology, College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China; 2. Shengli Oilfield Geologic Science Research Institute, Dongying 257000, China)
Abstract:A heat resisting and salt tolerant surfactant is synthesized, and the structure is analyzed by Infrared (IR). The sulfobe- taine surfactant is compounded with 25 million molecular weight of polymer, the surface and interfacial properties of the compound sys- tem are investigated. The experimental resuhs indicate that the product is the target one, the critical micelle concentration of sulfobe- taine surfactant is 2. 19 × 10-3 tool/L, the surface tension (γcmc) is 25.51 mN/m; with the polymer added, the cmc become 4. 09 ×10-3 mol/L, and the Tome become 26. 65 mN/m; the mass concentration of surfactant is in the range of 0. 8 g/L to 1.5 g/L, the water/crude oil interfacial tension is arrived ultra low value 10-3 mN/m from Shengli oilfield. It is conductive to form the emulsion due to the poly- mer added.
Keywords:Betaine surfactang  Surface tension  Interfacial tension  Emulsifying performance
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