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Hydrogen sorption properties of MgH2/NaBH4 composites
Authors:Sandra Kurko,Annalisa Aurora,Daniele Mirabile Gattia,Vittoria Contini,Amelia Montone,Željka Ra&scaron  ković-Lovre,Jasmina Grbović Novaković
Affiliation:1. Vin?a Institute of Nuclear Sciences, University of Belgrade, P.O. Box 522, 11000 Belgrade, Serbia;2. ENEA, Technical Unit Materials Technology, Research Centre of Casaccia, Via Anguillarese 301, 00123 Rome, Italy
Abstract:The hydrogen sorption properties of magnesium hydride–sodium borohydride composites prepared by means of high-energy ball milling under Ar atmosphere were investigated. Mutual influence of milling time and the content of NaBH4 were studied. Microstructural and morphological analyses were carried out using X-ray Diffraction (XRD), laser scattering measurements and Scanning Electron Microscopy (SEM), while kinetic analysis and cycling were performed in a Sievert's volumetric apparatus. It has been shown that low content of NaBH4 and short milling time are beneficial for hydrogen sorption kinetics.
Keywords:Hydrogen storage   MgH2/NaBH4 composites   Kinetics   Sorption cycling
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