Synthesis and advanced dehydrogenation properties of niobium-based ammine borohydride |
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Authors: | Meng Li Feng Yuan Qinfen Gu Xuebin Yu |
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Affiliation: | 1. Department of Materials Science, Fudan University, Shanghai 200433, China;2. Australian Synchrotron, 800 Blackburn Rd, Clayton 3168, Australia |
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Abstract: | In this paper, niobium-based ammine borohydride has been synthesized via a simple ball milling of NbCl5·5NH3 and MBH4 (M = Li, Na) with a molar ratio of 1:5. Thermogravimetric analysis–mass spectrometry (TGA–MS) and temperature-programmed-desorption (TPD) results revealed that the dehydrogenation of NbCl5·5NH3/5LiBH4 and NbCl5·5NH3/5NaBH4 mixtures showed a two-step decomposition process with a total of 8.1 wt.% and 11.2 wt.% pure hydrogen evolution upon heating to 250 °C, respectively. Isothermal TPD results showed that over 6 wt.% and 10.4 wt.% pure hydrogen were liberated from NbCl5·5NH3/5NaBH4 within 60 min at 150 °C and 220 °C, respectively. Fourier transform infrared spectroscopy (FTIR) and isotope tagging measurements demonstrated that the dehydrogenation mechanism of niobium-based ammine borohydride is not only based on the combination reaction of BH and NH groups, but the BH?HB and NH?HN homo-polar interactions also contribute to the H2 formation. |
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Keywords: | Niobium-based ammine borohydride Dehydrogenation Homo-polar interactions |
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