Phase Transformation of Hydrous-Zirconia Fine Particles Containing Cerium Hydroxide

Monoclinic hydrous-zirconia fine particles that contained cerium(IV) hydroxide (Ce(OH)₄) were heated from 200°C to 600°C, to investigate the phase transformation to CeO₂-doped tetragonal ZrO₂. Both ZrOCl₂·8H₂O and CeCl₃·7H₂O were dissolved in aqueous solutions and then boiled to prepare the hydrous-zirconia particles. The Ce(OH)₄-containing hydrous-zirconia particles were prepared by adding aqueous ammonia into the boiled solutions. The monoclinic-to-tetragonal ( m right arrow t ) phase transformation of the Ce(OH)₄-containing hydrous zirconias was observed at 300°C using X-ray diffraction (XRD). XRD and Brunauer-Emmett-Teller (BET) specific surface area measurements revealed that the Ce(OH)₄-containing hydrous zirconias had a tendency to transform from the monoclinic phase to the tetragonal phase at lower temperatures as the primary particle size of the hydrous zirconia decreased and the Ce(OH)₄ content increased. These tendencies for the m right arrow t phase transformation agree with the conclusions that have been derived from thermodynamic and kinetic considerations.