| 室温湿固化端异氰酸酯-聚丙烯酸酯的合成及应用 |
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| 引用本文： | 王志玲,王正,张书香,陈艳晶.室温湿固化端异氰酸酯-聚丙烯酸酯的合成及应用[J].高分子材料科学与工程,2006,22(1):56-59,63. |
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| 作者姓名： | 王志玲 王正 张书香 陈艳晶 |
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| 作者单位： | 1. 济南大学化学化工学院,山东,济南,250022
2. 中国林科院木材工业研究所,北京,100091 |
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| 基金项目： | 863课题基金资助(2002AA245141) |
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| 摘 要： | 用本体加成-聚合工艺,合成了一种新型单组分、无溶剂、室温湿固化端异氰酸酯-聚丙烯酸酯共聚物。考察了合成工艺、NCO/OH摩尔比、异氰酸酯种类、丙烯酸酯单体对其粘接性能及丙烯酸酯转化率的影响,用红外光谱对生成物的结构进行了表征。实验表明,M D I/PM D I质量比为1/2,NCO/OH摩尔比为15/1,丙烯酸酯单体采用半连续加料法,过氧化环己酮/N,N-二甲基苯胺复合引发,丙烯酸酯单体转化率可达到100%。用于橡木/聚丙烯(PP)粘接,PP破坏,剥离强度可达到15.4 N/cm。
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| 关 键 词： | 异氰酸酯 聚丙烯酸酯 过氧化环己酮/N N-二甲基苯胺 粘接 |
| 文章编号： | 1000-7555（2006）01-0056-04 |
| 收稿时间： | 2004-10-08 |
| 修稿时间： | 2004-10-082005-11-24 |
STUDY OF SYNTHESIS AND APPLICATION ON MOISTU-ACTIVATED AND COLD CURABLE POLYACRYLATE TERMINATED ISOCYANATE |
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| WANG Zhi-ling,WANG Zheng,ZHUANG Shu-xiang,CHEN Yan-jing.STUDY OF SYNTHESIS AND APPLICATION ON MOISTU-ACTIVATED AND COLD CURABLE POLYACRYLATE TERMINATED ISOCYANATE[J].Polymer Materials Science & Engineering,2006,22(1):56-59,63. |
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| Authors: | WANG Zhi-ling WANG Zheng ZHUANG Shu-xiang CHEN Yan-jing |
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| Affiliation: | 1. The College of Chemistry and Chemical Engineering, Jinan University, Jinan 250022, China; 2. Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, China |
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| Abstract: | Polyacrylate copolymer terminated isocyanate were synthesized by process of addition and polymerization of bulk,which are the novel one component,solvent free,moisture-activated curable at room temperature.The effects of synthetic process,NCO/OH molar ratio,isocyanate types,acrylate monomers and polymeric initiators on the adhesive properties and the conversation content of monomers were studied.The results showed that the conversion of 100% monomers can be achieved with MDI/PMDI mass ratio of 2,NCO/OH molar ratio of 15,cyclohexanone peroxide/N,N-dimethylaniline as initiator and by semi-continuous adding acrylate monomers,peel strength of(15.4) N/cm were achieved as used for adhesive of oak veneer-polypropylene.The chemical reaction was verified by FT-IR. |
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| Keywords: | isocyanates polyacrylates cyclohexanone peroxide/N N-dimethylanilin adhesion |
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