| 四唑基功能化的单壁碳纳米管的制备与表征 |
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| 引用本文： | 纪晓唐,卜建华,葛忠学,李陶琦,苏海鹏,刘庆,朱勇,肖啸. 四唑基功能化的单壁碳纳米管的制备与表征[J]. 含能材料, 2015, 23(1): 99-102 |
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| 作者姓名： | 纪晓唐 卜建华 葛忠学 李陶琦 苏海鹏 刘庆 朱勇 肖啸 |
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| 作者单位： | 西安近代化学研究所,陕西西安,710065 |
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| 摘 要： | 利用在单壁碳纳米管(SWCNTs)侧壁的重氮化反应,制备了四唑基共价键功能化的单壁碳纳米管(SWCNTs-CN4),红外衰减全反射光谱和拉曼光谱表明四唑基团结构完整,并且通过共价键引入到碳纳米管表面。X-射线光电子能谱(XPS)表明SWCNTsCN4中氮元素含量为14.8%,经XPS计算,SWCNTs上每100个碳原子上对应4.9个四唑基。
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| 关 键 词： | 分析化学 单壁碳纳米管 修饰 四唑基功能化 |
| 收稿时间： | 2014-02-23 |
| 修稿时间： | 2014-05-07 |
Preparation and Characterization of Tetrazolyl-functionalized Single Walled Carbon Nanotubes |
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| JI Xiao-tang,BU Jian-hu,GE Zhong-xue,LI Tao-qi,SU Hai-peng,LIU Qing,ZHU Yong and XIAO Xiao. Preparation and Characterization of Tetrazolyl-functionalized Single Walled Carbon Nanotubes[J]. Chinese Journal of Energetic Materials, 2015, 23(1): 99-102 |
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| Authors: | JI Xiao-tang BU Jian-hu GE Zhong-xue LI Tao-qi SU Hai-peng LIU Qing ZHU Yong XIAO Xiao |
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| Abstract: | The single-wall carbon nanotubes functional modified with tetrazoly groups(SWCNTs-CN4) was firstly prepared by diazo-reaction on the wall of SWCNTs, and was characterized. Attenuated total reflectance-fourier transform infrared spectroscopy (ATR-FTIR) and Raman spectroscopy show that the tetrazolyl groups are introduced to the surface of SWCNTs by covalent bond and hold the structure of five-ring. X-ray photoelectron spectroscopy (XPS) indicates that the N on the SWCNTs-CN4 is about 14.8%. The ratio of tetrazolyl groups to carbon atoms of SWCNTs-CN4 is about 4.9/100 by XPS calculation. |
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| Keywords: | analytical chemistry single-wall carbon nanotubes (SWCNTs) modification tetrazolyl-functionalization |
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