| 含氟阳离子憎水施胶剂的制备与表征 |
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| 引用本文： | 张俊苗,;付永山. 含氟阳离子憎水施胶剂的制备与表征[J]. 上海造纸, 2009, 0(4): 52-54 |
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| 作者姓名： | 张俊苗, 付永山 |
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| 作者单位： | [1]四川工商职业技术学院轻化工程系,四川成都611830; [2]西安宝莱特光电科技有限公司,陕西西安710021 |
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| 摘 要： | 以K2S2O8作引发剂，将甲基丙烯酸十二氟庚酯（MFAA）、丙烯酸丁酯（BAA）、丙烯酸羟丙酯（HPAA）和甲基丙烯酸二甲氨乙酯（DM）进行乳液聚合，制得了一种稳定的阳离子氟代聚丙烯酸酯乳液。用红外光谱（IR）、核磁共振氢谱（1HNMR）对共聚物结构进行了表征，并用透射电镜（TEM）对乳液的胶粒形态及粒径进行了测试。
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| 关 键 词： | 氟代丙烯酸酯 乳液聚合 憎水 施胶剂 |
Preparation and Characterization of Cationic Fluorinated Sizing Agent |
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| Affiliation: | Zhang Junmiao, Fu Yongshan (1.Department of Light Chemical Engineering, SiChuan Technology ＆ Business College, ChengDu, 611830, China; 2. Xi＇an Polymer Light Technologies Inc. Xi＇ an, 710021, China) |
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| Abstract: | Cationic fluorinated acrylate polymer emulsion was prepared by using monomer materials of dodecafluoro-heptyl methacrylate （MFAA）, butyl acrylate （BAA）, 2-Hydroxypropyl acrylate（HPAA） and dimethylaminoethyl methacrylate（DM） as a free radical initiator K2S2O8. Chemical structure of copolymer was characterized by infrared spectrum （IR） and proton nuclear magnetic resonance （1H NMR） and the particles and particle morphology of polymer emulsion were investigated by Transmission electron microscopy（TEM）. |
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| Keywords: | fluorinated acrylate emulsion polymerization water-repellent sizing agent |
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