| LiNi0.9Co0.1O2正极材料的EDTA络合法合成及其性能研究 |
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| 引用本文： | 刘景,温兆银,顾中华,张向峰. LiNi0.9Co0.1O2正极材料的EDTA络合法合成及其性能研究[J]. 无机材料学报, 2003, 18(4): 813 |
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| 作者姓名： | 刘景 温兆银 顾中华 张向峰 |
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| 作者单位： | 中国科学院上海硅酸盐研究所功能陶瓷工程与研究中心 上海 200050 |
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| 摘 要： | 采用络合法制备了锂离子电池的活性正极材料LiNi0.9Co0.1O2粉体,实验表明合成的LiNi0.9Co0.1O2粉体结晶良好,层状结构发育完善。电池充放电测试结果表明,其容量及循环性能与LiNi0.9Co0.1O2粉体的合成温度有关,其中900℃合成得到的LiNi0.9Co0.1O2材料具有最好的电化学性能,首次放电比容量高达120.5mAh/g,循环30次后可逆放电比容量仍高达118.8mAh/g,容量损失仅为1.4％。文中对容量退化的原因进行了分析。
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| 关 键 词： | LiNi0.9Co0.1O2 正极材料 络合法 锂离子电池 |
| 收稿时间： | 2002-07-09 |
| 修稿时间： | 2002-08-29 |
Synthesis by an EDTA-based Complexation Process and Characterization of LiNi0.9Co0.1O2 Cathode Materials |
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| LIU Jing,WEN Zhao-Yin,GU Zhong-Hua,ZHANG Xiang-Feng. Synthesis by an EDTA-based Complexation Process and Characterization of LiNi0.9Co0.1O2 Cathode Materials[J]. Journal of Inorganic Materials, 2003, 18(4): 813 |
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| Authors: | LIU Jing WEN Zhao-Yin GU Zhong-Hua ZHANG Xiang-Feng |
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| Affiliation: | Center of Functional Ceramic Research and Engineering; Shanghai Institute of Ceramics; Chinese Academy of Sciences; Shanghai 200050; China |
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| Abstract: | The layered LiNixCo1-xO2 compound was prepared by calcining a complex precursor at different temperatures. The physical properties of the synthesized cathode materials were discussed on the basis of structural analysis. The charge and discharge cycling of the cells containing the synthesized oxide as the positive electrode in conjunction with lithium metal and employing a non-aqueous electrolyte shows that LiNi0.9Co0.1O2 treated at 900℃ exhibits the best electrochemical performance. The first discharge capacity of LiNi0.9Co0.1O2 is 120.5 mAh/g with 30 cycle capacity loss of only 1.4%. The mechanisms of capacity degradation were investigated based on phase and microstructure analyses. |
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| Keywords: | LiNi0.9Co0.1O2 |
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