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嵌段共聚物PEO—PPO—PEO增韧环氧树脂的研究
引用本文:胡春林,周建萍,范红青.嵌段共聚物PEO—PPO—PEO增韧环氧树脂的研究[J].粘接,2009(6):60-63.
作者姓名:胡春林  周建萍  范红青
作者单位:南昌航空大学材料学院高分子材料与工程系,江西,南昌,330063
摘    要:采用嵌段共聚物PEO—PPO-PEO对环氧树脂进行增韧改性。结果表明,PEO—PPO—PEO对环氧树脂具有较好的增韧改性作用,PEO—PPO—PEO/EP/MeTHPA体系的冲击强度随着嵌段共聚物含量的增加而增大,而对拉伸强度影响较小。当F38质量分数为20%时,固化物的冲击强度能提高190%,而拉伸强度仅下降6.2%。TG测试结果表明,PEO—PPO—PEO的加入对环氧固化物的热性能影响不大。

关 键 词:环氧树脂  嵌段共聚物  增韧改性

Modification of epoxy resin by addition amphiphilic diblock copolymer PEO-PPO-PEO
HU Chun-lin,ZHOU Jian-ping,FAN Hong-qing.Modification of epoxy resin by addition amphiphilic diblock copolymer PEO-PPO-PEO[J].Adhesion in China,2009(6):60-63.
Authors:HU Chun-lin  ZHOU Jian-ping  FAN Hong-qing
Affiliation:School of Material Science and Engineering;Nanchang Aeronautical University;Nanchang;Jiangxi 330063;China
Abstract:Epoxy resin was modified by addition amphiphilic diblock copolymer PEO-PPO-PEO.The results showed that the impact strength of modified resin increased with increasing of content of the diblock copolymer,while the tensile strength reduced a little.When content of diblock copolymer F38 is 20%,by weight,the impact strength of cured resin can be improved by 190%),with only 6.2%reducing of tensile strength.The TG results of the modified resin indicated that addition of the diblock copolymer has little effect on ...
Keywords:epoxy resin  diblock copolymer  toughening modification  
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