| 无三苯CR/SBS/MMA/BA自交联环保型鞋用胶的合成与表征 |
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| 引用本文： | 张东亮,龚方红.无三苯CR/SBS/MMA/BA自交联环保型鞋用胶的合成与表征[J].中国胶粘剂,2003,12(6):33-36. |
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| 作者姓名： | 张东亮 龚方红 |
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| 作者单位： | 江苏工业学院材料系,江苏省,常州市,213016 |
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| 基金项目： | 江苏石油化工学院科技基金资助项目 |
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| 摘 要： | 在不含"三苯"的溶剂中,研究了氯丁橡胶(CR)、SBS、甲基丙烯酸甲酯(MMA)、丙烯酸丁酯(BA)、自交联剂N-羟甲基丙烯酰胺(NAM)及丙烯酸(AA)的多元共混接枝共聚,着重讨论了SBS用量、MMA/BA配比,复合交联剂NAM及AA用量、复合引发剂用量、聚合温度和聚合时间对胶粘剂粘合性能的影响,并用红外光谱对接枝产物进行了表征。研究结果表明:所研制的CR/SBS/MMA/BA/AA/NAM自交联环保型接枝胶对非极性鞋材的粘接性能优良。
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| 关 键 词： | CR/SBS/MMA/BA多元接枝共聚 自交联 环保 无三苯鞋用胶 |
| 文章编号： | 1004-2849(2003)06-0033-04 |
| 修稿时间： | 2003年1月23日 |
Synthesis and characterization of CR/SBS/MMA/BA environmentally friendly aromatic hydrocarbon-free and self-crosslinking adhesive for shoes |
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| ZHANG Dong-liang,GONG Fang-hong.Synthesis and characterization of CR/SBS/MMA/BA environmentally friendly aromatic hydrocarbon-free and self-crosslinking adhesive for shoes[J].China Adhesives,2003,12(6):33-36. |
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| Authors: | ZHANG Dong-liang GONG Fang-hong |
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| Abstract: | The polybasic graft copolymerization of CR?SBS?methyl methacrylate(MMA)?butyl acrylate(BA)?N-(hydroxymethyl) acrylamide (NAM) and acrylic acid (AA) was studied in aromatic hydrocarbon-free solvent. Effects of the amount of SBS? the MMA/BA monomer ratio?the amount of AA and NAM?composite initiator? reaction temperature and time on adhesive properties were mainly discussed, and the polybasic graft copolymer was characterized by IR. The result showed that the adhesive property of this self-crosslinking CR/SBS/MMA/BA/AA/NAM polybasic graft adhesive to non-polar shoe material is excellent. |
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| Keywords: | CR/SBS/MMA/BA polybasic graft copolymerization self-crosslinking environmental protection aromatic hydrocarbon-free adhesive for shoes |
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