Treatment of effluents from the regeneration of ion exchangers using the MD process

The membrane distillation (MD) process for the treatment of wastewater from ion-exchanger regeneration was proposed. The precipitation of salt deposits on the membrane surface was observed when such wastewater was directly used as a feed. A rapid decline of the permeate flux from 532 to 410 dm³/m²d was found. The problem of fouling was significantly diminished by the addition of Ca(OH)₂ to the wastewater followed by filtration. The improvement of MD module performance was achieved after such pretreatment. The degree of water recovery equal to 50% was obtained without significant variations of the permeate flux. However, when the pretreated feed was subjected to two-fold concentration, precipitation of the silicon compounds was observed. The deposit caused clogging of the inlets of capillary membranes and resulted in a gradual decline of the module efficiency. The two-fold concentrated feed was then treated by sedimentation and filtration, which permitted a further concentration of obtained retentate and enhanced the degree of water recovery to 75%.