| 采用唯象理论研究光聚合动力学 |
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| 引用本文： | 叶国东.采用唯象理论研究光聚合动力学[J].广东化工,2009,36(4):17-18. |
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| 作者姓名： | 叶国东 |
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| 作者单位： | 广州医学院,化学教研室,广东,广州,510182;法国上阿尔萨斯大学,普通光化学系,阿尔萨斯,米卢斯,68093 |
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| 基金项目： | 广州医学院博士启动基金 |
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| 摘 要： | 文章探讨紫外光固化的自加速现象，并用唯象理论从数学上作出阐述、考察了单体种类，光引发剂种类对动力学参数的影响，并对不同条件下该模型的参数进行了计算。结果表明，该数学模型能很好地量化在不同条件下光聚合反应的变化。
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| 关 键 词： | 光聚合 数学模型 紫外 动力学 自加速 |
Investigating the Kinetics of Photopolymerization with Phenomenological Theory |
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| Ye Guodong.Investigating the Kinetics of Photopolymerization with Phenomenological Theory[J].Guangdong Chemical Industry,2009,36(4):17-18. |
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| Authors: | Ye Guodong |
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| Affiliation: | Ye Guodong( Department of Chemistry, Guangzhou Medical College, Guangzhou 510182, China; 2. Department of Photochemistry, University of Haute Alsace, Mulhouse Cedex 68093, France) |
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| Abstract: | The paper investigated kinetics in UV-Curing by DPC and used phenomenological theory to interpret the autoacceleration behavior of photopolymerization. The influence of defferent photoinitiators and monomers were dicussed. The parameters of kinetics were obtained by the simulation analysis. As a consequence, the photopolymerization could be investigated quantitatively by this means. |
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| Keywords: | photopolymerization mathematical model UV kinetics autoacceleration |
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