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丝胶蛋白/丙烯酸/丙烯酰胺复合吸水材料的制备与吸水性能
引用本文:邓连霞,朱良均,闵思佳,杨明英,张海萍,林蓉,王雪云,王克波.丝胶蛋白/丙烯酸/丙烯酰胺复合吸水材料的制备与吸水性能[J].高分子材料科学与工程,2011(12):127-130.
作者姓名:邓连霞  朱良均  闵思佳  杨明英  张海萍  林蓉  王雪云  王克波
作者单位:浙江大学应用生物资源研究所
基金项目:国家自然科学基金资助项目(30771633);浙江省优先主题项目(2007C13043)
摘    要:以丝胶蛋白(SS)、丙烯酸(AA)和丙烯酰胺(AM)为主要原料,N,N′-亚甲基双丙烯酰胺(MBA)为交联剂,过硫酸铵(APS)为引发剂,采用水溶液聚合法制备了丝胶蛋白/丙烯酸/丙烯酰胺复合吸水材料,并考察了其在不同条件下的吸水性能。结果表明,SS/AA/AM复合吸水材料在去离子水、自来水、0.9%NaCl溶液中的吸水...

关 键 词:丝胶蛋白  丙烯酸/丙烯酰胺  吸水材料  吸水性能  热特性

Preparation and Water Absorbency Performance of Silk Sericine/Acrylic Acid/Acrylamide Composite Absorbent Material
Lianxia Deng,Liangjun Zhu,Sijiang Min,Minying Yang Haiping Zhang,Rong Lin,Xueyun Wang,Kebo Wang.Preparation and Water Absorbency Performance of Silk Sericine/Acrylic Acid/Acrylamide Composite Absorbent Material[J].Polymer Materials Science & Engineering,2011(12):127-130.
Authors:Lianxia Deng  Liangjun Zhu  Sijiang Min  Minying Yang Haiping Zhang  Rong Lin  Xueyun Wang  Kebo Wang
Affiliation:(Institute of Applied Bioresource Research,Zhejiang University,Hangzhou 310029,Zhejiang,China)
Abstract:Silk sericine/acrylic acid/acrylamide(SS/AA/AM) composite absorbent material were synthesized by silk sericine,acrylic acid and acrylamide in water when N,N′-methylenebisacrylamide(MBA) was used as crosslinker.and ammonium persulfate(APS) as initiator.The water absorbency performance under different conditions were investigated.The results show the absorbent ratio of SF/AA/AM superbabsorbent polymer in deionized water,tap water and 0.9% NaCl solution is 261 g/g~313 g/g,172 g/g~198 g/g,32 g/g~39 g/g respectively.The melting temperature and oxidative decomposition temperature of the synthesized polymer have changed,the melting temperature have changed from 223 ℃ to 226 ℃,proving that the silk fibroin had polymerized well with acrylic acid and acrylamide.
Keywords:silk sericine  acrylic acid/acrylamide  absorbent material  water absorption property  thermal characteristic
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