| PNPMI-b-P4VP-ZnS纳米复合物的RAFT合成及其光学性质可控性 |
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| 引用本文： | 董延茂,路建美,纪顺俊,严锋,徐庆锋,胡磊.PNPMI-b-P4VP-ZnS纳米复合物的RAFT合成及其光学性质可控性[J].高分子材料科学与工程,2011(8):35-38,42. |
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| 作者姓名： | 董延茂 路建美 纪顺俊 严锋 徐庆锋 胡磊 |
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| 作者单位： | 苏州大学材料与化学化工学部;苏州科技学院化学与生物工程学院 |
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| 基金项目： | 国家自然科学基金资助项目(20476066,20571054,20876101);江苏自然科学基金(BK2005031);江苏高技术项目(BE2008061)资助 |
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| 摘 要： | 以N-苯基马来酰亚胺（NPMI）和4-乙烯基吡啶-醋酸锌配合物（4VP-Zn（Ac）2）为单体,用可逆断裂链转移聚合（RAFT）方法合成了两亲性聚（N-苯基马来酰亚胺）-b-聚（4-乙烯基吡啶）-ZnS（PNPMI-b-P4VP-ZnS）高分子纳米复合物（PNCs）,用核磁共振（NMR）、X射线衍射（XRD）、扫描电镜...
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| 关 键 词： | 可逆断裂链转移聚合 聚(N-苯基马来酰亚胺)-b-聚(4-乙烯基吡啶) 纳米复合物 荧光 |
RAFT Synthesis and Optical Controllability of PNPMI-b-P4VP-ZnS Nanocomposites |
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| Yanmao Dong,Jianmei Lu,Shunjun Ji,Feng Yan,Qingfeng Xu,Lei Hu.RAFT Synthesis and Optical Controllability of PNPMI-b-P4VP-ZnS Nanocomposites[J].Polymer Materials Science & Engineering,2011(8):35-38,42. |
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| Authors: | Yanmao Dong Jianmei Lu Shunjun Ji Feng Yan Qingfeng Xu Lei Hu |
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| Affiliation: | 1(1.College of Chemistry,Chemical Engineering and Materials Science,Soochow University,Suzhou 215123,China;2.School of Chemistry and Bioengineering,University of Scienceand Technology of Suzhou,Suzhou 215009,China) |
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| Abstract: | The amphipathic poly(N-phenylmaleimide)-b-poly(4-vinylpyridine)-zinc acetate(PNPMI-b-P4VP-Zn(Ac)2) complex has been synthesized by reversible addition fragmentation chain transfer(RAFT) polymerization,using N-phenylmaleimide and 4-vinylpyridine-zinc acetate(4VP-Zn(Ac)2) as monomers.The products as prepared have been characterized by nuclear magnetic resonance spectrum(NMR),X-ray diffraction(XRD),scanning electron microscope(SEM) and transmission electron microscope(TEM).The ZnS mass fraction increases from 8.2% to 12.6% with the block copolymerization time increasing from 1h to 30h.The particle size of ZnS also increases from 3 nm to 200 nm,accompanied with the crystal style conversion of ZnS from cubic to hexagonal.The photoluminescence(PL) intensity of PNPMI-b-P4VP decreases with the increasing block copolymerization time,however,the PL intensity of ZnS increases.Results show that,the fluorescence resonance energy transfer properties between PNPMI-b-P4VP and ZnS are controllable by RAFT method.The PNPMI-b-P4VP-ZnS FRET probe shows a potential application in the biologic field. |
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| Keywords: | RAFT poly(N-phenylmaleimide)-b-poly(4-vinylpyridine) nanocomposite photoluminescence |
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