| N-乙烯基吡咯烷酮的反向原子转移自由基聚合 |
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| 引用本文： | 肖成贵,易国斌,肖宏,黄云薇. N-乙烯基吡咯烷酮的反向原子转移自由基聚合[J]. 高分子材料科学与工程, 2011, 0(6): 18-21 |
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| 作者姓名： | 肖成贵 易国斌 肖宏 黄云薇 |
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| 作者单位： | 广东工业大学轻工化工学院 |
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| 基金项目： | 广东省自然科学基金资助项目(07001781);广东省科技计划项目(2007B010600058,2006B13801005) |
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| 摘 要： | 以AIBN为引发剂、FeCl3为催化剂、PPh3为配体,在乙腈中实现了N-乙烯基吡咯烷酮(NVP)的反向原子转移自由基聚合(RATRP).动力学研究表明,聚合产物聚乙烯基吡咯烷酮(PVP)的分子量与单体转化率成线性关系,反应10 h后,PVP的平均分子量(-M)n为2964,分子量分散系数(PDI)为1.18.以含有端...
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| 关 键 词： | 聚乙烯基吡咯烷酮 反向原子转移自由基聚合 甲基丙烯酸甲酯 嵌段共聚物 |
Reverse Atom Transfer Radical Polymerization of N-Vinylpyrrolidone |
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| Chenggui Xiao,Guobin YI,Hong Xiao,Yunwei Huang. Reverse Atom Transfer Radical Polymerization of N-Vinylpyrrolidone[J]. Polymer Materials Science & Engineering, 2011, 0(6): 18-21 |
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| Authors: | Chenggui Xiao Guobin YI Hong Xiao Yunwei Huang |
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| Affiliation: | (Faculty of Light and Chemical Engineering,Guangdong University of Technology,Guangzhou 510006,China) |
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| Abstract: | The reverse atom transfer radical polymerization（RATRP） of N-vinylpyrrolidone（NVP）,with acetonitrite as solvent,azodiisobutyronitrile（AIBN） as initiator,FeCl3 as catalyst and PPh3 as ligand was carried out successfully.The kinetic results suggest a linear increase in experimental number-average molecular weight（Mn） with increase of monomer conversion.The Mn and the polydispersity（PDI） are 2964 and 1.18 respectively after 10 hours.The poly（N-vinylpyrrolidone）（PVP） ended with chlorine groups with narrow polydispersity can initiate atom transfer radical polymerization of methyl methacrylate（MMA） to produce well-defined PVP-b-PMMA.The block copolymer was characterized by gel permeation in chromatography（GPC）,Fourier transform infrared spectrum（FTIR） and 1H nuclear magnetic resonance spectrum（1H-NMR）. |
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| Keywords: | poly(N-vinylpyrrolidone) reverse atom transfer radical polymerization methacrylate block copolymer |
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