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PMMA/CaCO3纳米复合材料的制备与性能
引用本文:刘小育,常成功,徐惠,范宗良. PMMA/CaCO3纳米复合材料的制备与性能[J]. 高分子材料科学与工程, 2011, 0(3): 154-156,161
作者姓名:刘小育  常成功  徐惠  范宗良
作者单位:兰州理工大学石油化工学院
基金项目:甘肃省自然科学基金资助项目(2007JS05348);甘肃省国际科技合作计划项目(0804WCGA125)
摘    要:用硅烷偶联剂KH-570对纳米CaCO3表面进行改性处理,采用原位聚合法制备了聚甲基丙烯酸甲酯(PMMA)/CaCO3纳米复合材料,用溶解实验、扫描电镜(SEM)、红外光谱(FT-IR)等方法对纳米CaCO3粒子和PMMA基体之间的界面相容性进行了表征,考察了复合材料的力学性能.结果表明,纳米CaCO3在基体中可能起到...

关 键 词:聚甲基丙烯酸甲酯  纳米CaCO3  纳米复合材料  力学性能

Preparation and Properties of PMMA/CaCO3 Nanocomposites
Xiaoyu Liu,Chenggong Chang,Hui Xu,Zongliang Fan. Preparation and Properties of PMMA/CaCO3 Nanocomposites[J]. Polymer Materials Science & Engineering, 2011, 0(3): 154-156,161
Authors:Xiaoyu Liu  Chenggong Chang  Hui Xu  Zongliang Fan
Affiliation:g(College of Petrochemical Technology,Lanzhou University of Technology,Lanzhou 730050,China)
Abstract:The surface of the nano-calcium carbonate was modified with KH-570,the polymethyl methacrylate(PMMA)/ CaCO3 nanocomposites were prepared by in situ polymerization.The interfacial compatibility between nano-CaCO3 and PMMA matrix was characterized by dissolution,scanning electron microscope(SEM),Fourier transform infrared spectrum(FT-IR),the mechanical property of nanocomposites was studied.The results show that nano-CaCO3 may be crosslinking points in the matrix.There are good dispersion and interfacial adhesion between the modified nano-CaCO3 and the PMMA matrix.As the content of nano-CaCO3 increases to 1%,its tensile strength increases by about 35%,impact strength increases by about 70%,flexural strength increases by about 60%.
Keywords:PMMA  nano-CaCO3  nanocomposite  mechanical properties
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