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固化条件对改性CE体系的固化和性能的影响
引用本文:陈强,胡柏星,吴石山,沈健. 固化条件对改性CE体系的固化和性能的影响[J]. 高分子材料科学与工程, 2011, 0(7): 62-65
作者姓名:陈强  胡柏星  吴石山  沈健
作者单位:南京大学化学化工学院;南京师范大学化学和环境学院
摘    要:研究了不同固化条件对氰酸酯树脂(CE)/环氧树脂(EP)(60/40)体系和CE/EP/丁腈橡胶(A)(71/4/25)体系的固化反应以及CE/EP(60/40)和CE/EP/A(71/4/25)膜性能的影响。CE/EP和CE/EP/A体系固化程度随加热时间延长和温度升高而提高。CE/EP膜柔韧性差。随着加热温度升高,...

关 键 词:氰酸酯树脂/环氧树脂/丁腈橡胶体系  固化条件  固化程度  性能

Effects of Curing Conditions on Cure and Properties of Modified CE System
Qiang Chen,Baixing Hu,Shishan Wu,Jian Shen. Effects of Curing Conditions on Cure and Properties of Modified CE System[J]. Polymer Materials Science & Engineering, 2011, 0(7): 62-65
Authors:Qiang Chen  Baixing Hu  Shishan Wu  Jian Shen
Affiliation:1,2(1.Department of Polymer Science and Engineering,School of Chemistry and ChemicalEngineering,Nanjing University,Nanjing 210093,China;2.College of Chemistry andEnvironment Science,Nanjing Normal University,Nanjing 210097,China)
Abstract:The effects of different curing conditions on curing reaction of cyanate ester resins(CE)/epoxy resin(EP)(60/40) system and CE/EP/chemigum(A)(71/4/25) system,as well as the properties of the corresponding films were investigated.The curing degree increases with increasing heating time and temperature in both CE/EP and CE/EP/A system.The CE/EP film has poor flexility.The thermal stability of CE/EP/A film was increased with increasing heating temperature under the same heating time;the temperature of thermal decomposition was 367.3 ℃ for the film heated for 2 h at 110 ℃,130 ℃ and 150 ℃,respectively.The impact strength and flexility of CE/EP/A film prepared in this paper are 50 kg·cm and 15 mm.With increasing the heating temperature,the tensile strength and Young’s modulus of CE/EP/A film enhance,while its elongation at break decreased.
Keywords:CE/EP/A system  curing condition  curing degree  property
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