| 甲基丙烯酸化核壳结构聚合物的制备及对尼龙6的改性 |
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| 引用本文： | 赵海燕,李艳敏,王占京,张立群,瞿雄伟. 甲基丙烯酸化核壳结构聚合物的制备及对尼龙6的改性[J]. 高分子材料科学与工程, 2011, 0(8): 146-149 |
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| 作者姓名： | 赵海燕 李艳敏 王占京 张立群 瞿雄伟 |
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| 作者单位： | 河北工业大学高分子科学与工程研究所;北京化工大学材料科学与工程学院 |
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| 基金项目： | 河北省自然科学基金资助项目(E2010000107) |
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| 摘 要： | 采用种子乳液聚合方法制备了一系列交联度不同的核壳结构聚丙烯酸丁酯/甲基丙烯酸甲酯-甲基丙烯酸共聚物Poly（BA/MMA-co-MAA）,简称PBMMA,单体总转化率达99.4%,乳胶粒径为302 nm,且理论值与实测值基本一致,说明该体系没有明显的二次成核过程。当交联剂质量分数为0.5%时,尼龙6/PBMMA（100...
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| 关 键 词： | 乳液聚合 甲基丙烯酸 核壳结构聚合物 增韧 尼龙6 |
Preparation of Functionalized Core-Shell Structural Polymer with Methacrylic Acid and Modifying Nylon 6 |
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| Haiyan Zhao,Yanmin Li,Zhanjing Wang,Liqun Zhang,Xiongwei Qu. Preparation of Functionalized Core-Shell Structural Polymer with Methacrylic Acid and Modifying Nylon 6[J]. Polymer Materials Science & Engineering, 2011, 0(8): 146-149 |
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| Authors: | Haiyan Zhao Yanmin Li Zhanjing Wang Liqun Zhang Xiongwei Qu |
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| Affiliation: | 1(1.Institute of Polymer Science and Engineering,Hebei University of Technology,Tianjin 300130,China;2.School of Materials Science and Engineering,Beijing University of Chemical Technology,Beijing 100074,China) |
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| Abstract: | A series of poly(BA/MMA-co-MAA) core/shell polymer(PBMMA) with different crosslinking densities were prepared by seeded emulsion polymerization.Gravimetric analysis was used to measure the conversion of monomer to polymer throughout the reactions and revealed that the polymerizations have proceeded under monomer-starved conditions(the final conversion>99.4%).The good agreement shown between experimental and theoretical particle diameters throughout the polymerization for all latexes provided strong evidence that the latex particles are grown without significant secondary nucleation.When using 0.5% crosslinking agent(Allyl methacrylate,ALMA) by mass fraction,the notched Izod impact strength of PA6/PBMMA(100/20) reaches a maximal value.DMA spectra showed that the broaden breadth of the transition zone at low temperature glass transition region and the weaken magnitude of loss peak of nylon 6(Tα) improve the compatibility between nylon 6 matrix and PBMMA particles.The SEM observation verified the results of modifying nylon 6. |
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| Keywords: | emulsion polymerization methacrylic acid core-shell polymer toughening nylon 6 |
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