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壳聚糖涂布淀粉基复合材料的耐湿热性能
引用本文:林宝凤,黎演明,周妤莲,李磊,杜予民. 壳聚糖涂布淀粉基复合材料的耐湿热性能[J]. 高分子材料科学与工程, 2011, 0(5): 75-77,81
作者姓名:林宝凤  黎演明  周妤莲  李磊  杜予民
作者单位:广西大学化学化工学院;武汉大学资源与环境科学学院
基金项目:国家自然科学基金资助项目(50263001)
摘    要:采用热压共混、涂布的方法制备了壳聚糖涂布淀粉基复合材料.红外光谱和扫描电镜研究表明该复合材料有着良好的相容性,壳聚糖溶液与基材间通过氢键作用而形成致密涂层;用两种湿热处理方法研究了该复合材料的耐湿热性能,结果显示,壳聚糖涂布能显著提高材料的耐湿热性能.经水蒸汽熏蒸30 min后,壳聚糖涂布使材料的吸水率从72.5%降低...

关 键 词:壳聚糖  淀粉基复合材料  涂布  耐湿热性能

Moisture-Thermo-Resistant Properties of Starch-Based Composite Coating with Chitosan
Baofeng Lin,Yanming Li,Yulian Zhou,Lei Li,Yumin Du. Moisture-Thermo-Resistant Properties of Starch-Based Composite Coating with Chitosan[J]. Polymer Materials Science & Engineering, 2011, 0(5): 75-77,81
Authors:Baofeng Lin  Yanming Li  Yulian Zhou  Lei Li  Yumin Du
Affiliation:1.College of Chemistry and Chemical Engineering,Guangxi University,Nanning 530004,China;2.College of Resource and Environmental Science,Wuhan University,Wuhan 430079,China)
Abstract:Starch-based composite coating with chitosan was prepared through blend under hot-pressing and coating treatment.The Fourier transform infrared spectrum(FT-IR) and scanning electron microscope(SEM) results show that the blend has a good compatibility,strong hydrogen bond exists between chitosan and other components resulting to form compact coating on the surface of composition.The moisture-thermo-resistant properties of the composite have been researched by two different moisture heat treatment methods.It is indicated that the moisture-thermo-resistant properties obviously improves after coating with chitosan.Coating chitosan can decreases the water absorption from 72.5% to 40.3% and increases the rate of remaining tensile strength from 62.9% to 95.7% after the composites had been treatment in water vapor for 30 min;Coating chitosan also can increases the rate of remaining tensile strength from 15.9% to 39.9% after socked in water of 50 ℃ for 30 min.
Keywords:chitosan  starch-based composite  coating  moisture-thermo-resistant properties
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