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Comparison of different advanced oxidation processes for phenol degradation
Authors:Esplugas Santiago  Giménez Jaime  Contreras Sandra  Pascual Esther  Rodríguez Miguel
Affiliation:Departamento de Ingenieria Química y Metalurgia de la Universidad de Barcelona, Spain.
Abstract:Advanced Oxidation Processes (O3, O3/H2O2, UV, UV/O3, UV/H2O2, O3/UV/H2O2, Fe2+ /H2O2 and photocatalysis) for degradation of phenol in aqueous solution have been studied in earlier works. In this paper, a comparison of these techniques is undertaken: pH influence, kinetic constants, stoichiometric coefficient and optimum oxidant/pollutant ratio. Of the tested processes, Fenton reagent was found to the fastest one for phenol degradation. However, lower costs were obtained with ozonation. In the ozone combinations, the best results were achieved with single ozonation. As for the UV processes, UV/H2O2 showed the highest degradation rate.
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