| 导电高分子与丙烯酸酯的接枝共聚反应研究 |
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| 引用本文： | 黄智敏,王玉华,邓安民.导电高分子与丙烯酸酯的接枝共聚反应研究[J].广州化工,2009,37(3):94-95. |
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| 作者姓名： | 黄智敏 王玉华 邓安民 |
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| 作者单位： | 南昌航空大学院环化学院,江西,南昌,330063 |
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| 摘 要： | 通过β-噻吩丙烯酸甲酯的自由基聚合，获得了聚（噻吩丙烯酸甲酯）（P-TAc）。GPC测得其数均分子量为2．4×10^4。化学氧化（P—TAc）获得聚丙烯酸甲酯-聚噻吩接枝共聚物。用FTIR光谱和Raman光谱确定了结构。材料的电导率为0．15S·cm^-4。
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| 关 键 词： | 聚噻吩 接枝共聚 聚噻吩丙烯酸甲酯 丙烯酸酯 |
Study on the Graft Copolymerization of Conducting Polymer and Acrylate |
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| HUANG Zhi-min,WANG Yu-hua,DENG An-min.Study on the Graft Copolymerization of Conducting Polymer and Acrylate[J].GuangZhou Chemical Industry and Technology,2009,37(3):94-95. |
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| Authors: | HUANG Zhi-min WANG Yu-hua DENG An-min |
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| Affiliation: | (School of Environment and Engineering Chemistry, Nanchang Hangkong University, Jiangxi Nanchang 330063, China) |
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| Abstract: | Poly（3-thienyl）methylacrylate （P-tAc） was synthesized by radical polymerization of 3-thienyl methylacrylate. The average molecular weight was measured to be 2.4 × 10^4. Graft copolymer of poly（methylacrylate）-polythiophene was obtained by chemical oxidation of PE. The structures of the polymers were characterized by FTIR and Raman spectra. The conductivity of the material was 0.15 S·cm^-1. |
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| Keywords: | polythiophene copolymer poly （3-thiengl） methylacrylate acrylate |
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