Zur Elektrodenkinetik von Reinst – Eisen im Phosphatelektrolyten bei Feststoffeinschlag (Simulation von Erosionskorrosion)

Electrode kinetics of high purity iron in phosphate electrolytes under solid particle impact (Simulation of erosion corrosion) Erosion-corrosion of high purity iron was simulated by means of a vibration cell in a neutral phosphate electrolyte. The investigations were carried out to explain the initiation processes of this type of corrosion. The results confirm the general conception of the central role of reaction layer destruction in erosion-corrosion processes. Under these conditions a qualitative change in reaction layer formation occur. By solid impact the layers are destroyed locally and so conditions of pit nucleation exist. The destruction of the layers depends on the action of shear forces resulting from tensile or compressive strains.