Thermodynamic Assessment of PrCl3-CaCl2 and NdCl3-CaCl2 Systems |
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| Authors: | Yu Wang Yimin Sun |
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| Affiliation: | (1) Department of Chemistry and Materials Engineering, Hefei University, Hefei, 230022, Anhui, People’s Republic of China;(2) College of Chemistry and Materials Science, Anhui Normal University, Wuhu, 241000, Anhui, People’s Republic of China |
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| Abstract: | By using the CALPHAD technique, an assessment of the binary PrCl3-CaCl2 and NdCl3-CaCl2 systems have been carried out. From measured phase equilibrium data and experimental integral properties, the PrCl3-CaCl2 and NdCl3-CaCl2 phase diagrams were optimized and calculated. A set of thermodynamic functions has been optimized based on an interactive computer-assisted analysis. The calculated results by present method agree well with the experimental data. |
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