Liquid phase formation in the system Al2O3–Y2O3–AlN: Part II. Thermodynamic assessment |
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Authors: | O Fabrichnaya D Pavlyuchkov R Neher M Herrmann HJ Seifert |
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Affiliation: | 1. Institut für Werkstoffwissenschaft der TU Bergakademie Freiberg, 09599 Freiberg, Germany;2. Fraunhofer Institut für keramische Technologien und Systeme, 01277 Dresden, Germany;3. Institut für Angewandte Materialien am Karlsruher Institut für Technologie, 76344 Eggenstein-Leopoldshafen, Germany |
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Abstract: | The mixing parameters of liquid phase in the Al2O3–Y2O3–AlN system were assessed based on differential thermal analysis (DTA) and scanning electron microscopy combined with energy dispersive X-ray spectroscopy (SEM/EDX) investigations of selected compositions. Phase diagram of the Y2O3–AlN system was calculated. Liquidus surface of the Al2O3–Y2O3–AlN system was constructed and compared with experimental results on primary crystallisation fields. Calculated temperatures of invariant reactions were in agreement with DTA results. Vertical sections of the Al2O3–Y2O3–AlN system were calculated and compared with experimental data |
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Keywords: | Aluminium nitride Alumina Yttria CALPHAD method Phase diagram |
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