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废轮胎二氧化碳活化借助析因设计的系统分析(英文)
引用本文:P.P.M.Fung,W.H.Cheung,G.McKay. 废轮胎二氧化碳活化借助析因设计的系统分析(英文)[J]. 中国化学工程学报, 2012, 20(3): 497-504. DOI: 10.1016/S1004-9541(11)60211-5
作者姓名:P.P.M.Fung  W.H.Cheung  G.McKay
作者单位:Kay Department of Chemical and Biomolecular Engineering, the Hong Kong University of Science and Technology, Hong Kong, China
基金项目:support of the Hong Kong University of Science and Technology through the UROP program
摘    要:In this study,waste tire was used as raw material for the production of activated carbons through pyrolysis.Tire char was first produced by carbonization at 550℃ under nitrogen.A two factorial design was used to optimize the production of activated carbon from tire char.The effects of several factors controlling the activation process,such as temperature(850-950 ℃),time(2-6 h) and percentage of carbon dioxide(70%-100%) were investigated.The production was described mathematically as a function of these three factors.First order modeling equations were developed for surface area,yield and mesopore volume.It was concluded that the yield,BET surface area and mesopore volume of activated carbon were most sensitive to activation temperature and time while percentage of carbon dioxide in the activation gas was a less significant factor.

关 键 词:activated carbon  waste tire  factorial design  carbon dioxide  
收稿时间:2012-02-06

Systematic Analysis of Carbon Dioxide Activation of Waste Tire by Factorial Design
P.P.M.Fung,W.H.Cheung and G.McKay. Systematic Analysis of Carbon Dioxide Activation of Waste Tire by Factorial Design[J]. Chinese Journal of Chemical Engineering, 2012, 20(3): 497-504. DOI: 10.1016/S1004-9541(11)60211-5
Authors:P.P.M.Fung  W.H.Cheung  G.McKay
Affiliation:Kay Department of Chemical and Biomolecular Engineering, the Hong Kong University of Science and Technology, Hong Kong, China
Abstract:In this study,waste tire was used as raw material for the production of activated carbons through pyrolysis.Tire char was first produced by carbonization at 550℃ under nitrogen.A two factorial design was used to optimize the production of activated carbon from tire char.The effects of several factors controlling the activation process,such as temperature(850-950 ℃),time(2-6 h) and percentage of carbon dioxide(70%-100%) were investigated.The production was described mathematically as a function of these three factors.First order modeling equations were developed for surface area,yield and mesopore volume.It was concluded that the yield,BET surface area and mesopore volume of activated carbon were most sensitive to activation temperature and time while percentage of carbon dioxide in the activation gas was a less significant factor.
Keywords:activated carbon  waste tire  factorial design  carbon dioxide
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