| 固体酸催化剂在Friedel-Crafts反应中的应用 |
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| 引用本文： | 刘玉芝,王桂荣,赵新强,王延吉.固体酸催化剂在Friedel-Crafts反应中的应用[J].精细石油化工,2011,28(4):16-22. |
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| 作者姓名： | 刘玉芝 王桂荣 赵新强 王延吉 |
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| 作者单位： | 河北工业大学化工学院,天津,300130 |
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| 基金项目： | 河北省自然科学基金资助项目(B2007000016) |
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| 摘 要： | 介绍了近年来沸石类催化剂、固体杂多酸及其盐催化剂、固体超强酸SO2-4/MxOy催化剂、高分子酸性催化剂、黏土类催化剂在Friedel-Crafts酰基化反应和Friedel-Crafts烷基化反应中的研究进展.许多固体酸催化剂有其独特的催化特性,但在Friedel-Crafts反应领域仍处于实验室研究阶段,对Frie...
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| 关 键 词： | Friedel-Crafts酰基化反应 Friedel-Crafts烷基化反应 固体酸 催化剂 |
PROGRESS IN APPLICATION OF SOLID ACIDS FOR FRIEDEL-CRAFTS REACTIONS |
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| LiuYuzhi,Wang Guirong,Zhao Xinqiang,Wang Yanji.PROGRESS IN APPLICATION OF SOLID ACIDS FOR FRIEDEL-CRAFTS REACTIONS[J].Speciality Petrochemicals,2011,28(4):16-22. |
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| Authors: | LiuYuzhi Wang Guirong Zhao Xinqiang Wang Yanji |
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| Affiliation: | Liu Yuzhi,Wang Guirong,Zhao Xinqiang and Wang Yanji (School of Chemical Engineering and Technology,Hebei University of Technology,Tianjin 300130,China) |
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| Abstract: | Friedel-Crafts reaction is widely used in organic chemistry.Friedel-Crafts acylation is one of the main reactions for the preparation of aromatic ketones,while Friedel-Crafts alkylation is the most important reaction for the formation of carbon-carbon bonds in organic synthesis.This paper presents a review on the application of zeolite,heteropoly acids and their salts,solid super acids SO_4~(2-)/M_xO_y, trifluoro-methanesulfonic acid and clay catalysts in the reactions of Friedel-Crafts reaction.Solid acid ... |
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| Keywords: | Friedel-Crafts acylation reactions Friedel-Crafts alkylation reactions solid acids catalyst |
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