| 固体超强酸SO4^2-/ZrO2和S2O8^2-/ZrO2催化合成环己烯 |
| |
| 引用本文： | 赵强,孟双明,王俊丽,郭永,樊月琴.固体超强酸SO4^2-/ZrO2和S2O8^2-/ZrO2催化合成环己烯[J].陕西化工,2010(10):1510-1513. |
| |
| 作者姓名： | 赵强 孟双明 王俊丽 郭永 樊月琴 |
| |
| 作者单位： | 山西大同大学化学与化工学院,山西大同037009 |
| |
| 基金项目： | 山西大同大学校级科研项目（2009K3 2010Q11） |
| |
| 摘 要： | 应用固体酸催化剂SO42-/ZrO2和S2O82-/ZrO2作为环己醇的脱水剂,成功地制备了环己烯,并对反应时间、反应温度、催化剂的用量等对脱水反应的影响进行了探讨,实验结果表明,SO42-/ZrO2和S2O82-/ZrO2是环己醇脱水制备环己烯的良好催化剂,并且反应时间短、后处理容易、催化剂用量少、可以重复使用、收率高。脱水反应的最佳工艺条件为：催化剂用量为环己醇质量的6%,反应时间为0.9 h,反应温度为150℃,催化剂用量为环己醇质量的6%。
|
| 关 键 词： | 环己烯 环己醇 固体超强酸 催化 |
Synthesis of cyclohexene by solid super acid catalyst SO4^2-/ZrO2 and S2O8^2-/ZrO2 |
| |
| ZHAO Qiang,MENG Shuang-ming,WANG Jun-li,GUO Yong,FAN Yue-qin.Synthesis of cyclohexene by solid super acid catalyst SO4^2-/ZrO2 and S2O8^2-/ZrO2[J].Applied Chemical Industry,2010(10):1510-1513. |
| |
| Authors: | ZHAO Qiang MENG Shuang-ming WANG Jun-li GUO Yong FAN Yue-qin |
| |
| Affiliation: | (School of Chemistry and Chemical Engineering,Shanxi Datong University,Datong 037009,China) |
| |
| Abstract: | Cyclohexene was prepared by applying a novel solid acid catalyst SO2-4/ZrO2 and S2O2-8/ZrO2 as dehydration catalyst.The effect of catalyst amount,temperature and reaction time on the dehydration reacation had been investigated.The results showed that SO2-4/ZrO2 and S2O2-8/ZrO2 possessed many advantages such as shorter reaction time,higher yield,smaller catalyst amount,being disposable and reusable.The optimal conditions for the reaction were as follows： catalyst was equal to 6% by the mass of the total reaction stock,reaction temperature 150 ℃,reaction time 0.9 h. |
| |
| Keywords: | cyclohexanol cyclohexene solid super acid catalytic |
| 本文献已被 维普 等数据库收录！ |
|
