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Phase selection in highly undercooled Fe-B eutectic alloy melts
作者姓名:杨长林  饧根仓  卢一平  陈豫增  周尧和
作者单位:State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072, China
摘    要:

关 键 词:Fe-B合金  共晶合金  过冷度  相位选择  亚稳相
收稿时间:2005-05-23
修稿时间:2005-11-04

Phase selection in highly undercooled Fe-B eutectic alloy melts
Chang-lin YANG, Gen-cang YANG, Yi-ping LU, Yu-zeng CHEN,Yao-he ZHOU.Phase selection in highly undercooled Fe-B eutectic alloy melts[J].Transactions of Nonferrous Metals Society of China,2006,16(1):39-43.
Authors:Chang-lin YANG  Gen-cang YANG  Yi-ping LU  Yu-zeng CHEN  Yao-he ZHOU
Affiliation:State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072, China
Abstract:The high undercooling technique by molten glass slag purification and cyclical superheating in Ar atmosphere was applied to bulk Fe-B alloy melts. A hypercooling was achieved which suppressed the formation of stable phase and consequently promoted the nucleation of metastable phase. Fe-17%B and Fe-20%B alloys were investigated, respectively. TEM and X-ray powder diffraction analyses verify the formation of metastable phase in the highly tmdercooled Fe-B alloy melts. Besides, the critical nucleation work of Fe2B and Fe3B phases was calculated to predict phase selection in the undercooled melts. The results show that the metastable phase formation is a function of the undercooling achieved prior to nucleation. And the amount of undercooling is an important factor in determining microstructural development by controlling phase selection in the undercooled melts.
Keywords:Fe-B eutectic alloy  metastable phase  phase selection  hypercooling
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