| 食品接触用再生PET制品中非有意/有意添加物迁移量的筛查及安全评估 |
| |
| 引用本文： | 董犇,黎梓城,郑建国,刘中勇,陈胜,李丹,林勤保,钟怀宁.食品接触用再生PET制品中非有意/有意添加物迁移量的筛查及安全评估[J].食品工业科技,2021,42(18):252-260. |
| |
| 作者姓名： | 董犇 黎梓城 郑建国 刘中勇 陈胜 李丹 林勤保 钟怀宁 |
| |
| 作者单位： | 1.广州海关技术中心，国家食品接触材料检测重点实验室（广东），广东广州 5106232.中国检验认证集团广东有限公司，广东广州 5106233.暨南大学，包装工程研究所，产品包装与物流广东普通高校重点实验室，广东珠海 5190704.中国食品接触材料可持续发展工作组，广东广州 510070 |
| |
| 基金项目： | 国家重点研发计划项目（2016YFF0203705）；广州海关科研项目（2020GZCK-026，2021GZCK12） |
| |
| 摘 要： | 为评估再生PET材料中非有意/有意添加物的迁移风险，采用液相四极杆飞行时间质谱、气相色谱串联质谱和顶空串联气相色谱法建立了再生PET制品中非有意/有意添加物筛查的方法，并对迁移实验所得食品模拟物进行检测。结果表明，共筛查出了6个化合物，其中油酸甲酯、棕榈酸甲酯、三甘醇辛酸癸酸酯和三乙二醇二异辛酸酯等4个化合物是有意添加物，亚油酸甲酯和1, 2-双-（4-羧基-苯甲酰基）-乙烷是非有意添加物。检出的化合物均未在GB 9685-2016食品安全国家标准中列出，是未被允许使用的化学物质。依据毒理学关注阈值法评估所检出的化合物均为Cramer Ⅰ类物质，结合膳食暴露条件评估它们的暴露量大大低于安全暴露阈值1.8 mg/人/d，对人体健康产生危害的可能性较低。
|
| 关 键 词： | 再生PET 有意/非有意添加物 迁移 安全评估 |
| 收稿时间： | 2021-01-15 |
Identification and Safety Assessment of the Migration of Intentionally and Non-intentionally Added Substances in Food Contact Recycled PET Product |
| |
| DONG Ben,LI Zicheng,ZHENG Jianguo,LIU Zhongyong,CHEN Sheng,LI Dan,LIN Qinbao,ZHONG Huaining.Identification and Safety Assessment of the Migration of Intentionally and Non-intentionally Added Substances in Food Contact Recycled PET Product[J].Science and Technology of Food Industry,2021,42(18):252-260. |
| |
| Authors: | DONG Ben LI Zicheng ZHENG Jianguo LIU Zhongyong CHEN Sheng LI Dan LIN Qinbao ZHONG Huaining |
| |
| Affiliation: | 1.National Reference Laboratory for Food Contact Material (Guangdong), Guangzhou Customs District Technology Center, Guangzhou 510623, China2.China Certification and Inspection Group Guangdong Co., Ltd., Guangzhou 510623, China3.Key Laboratory of Product Packaging and Logistics, Packaging Engineering Institute, Jinan University, Zhuhai 519070, China4.Working Group on China Sustainable Development of Food Contact Materials, Guangzhou 510070, China |
| |
| Abstract: | In order to assess the migration risk of non-intentional/intentional added substances to recycled PET materials, a method of screening these substances for recycled PET products was established using liquid chromatography-quadrupole-time of flight-mass spectrometry, gas chromatography-mass spectrometry and head-space gas chromatography-mass spectrometry. Results showed that: A total of 6 compounds were screened in food simulations after migration experiments, of which 4 substances, such as methyl oleate, methyl palmitate, triethylene glycol bis(2-ethylhexanoate) and triethylene glycol caprate caprylate were intentional added substances, methyl linoleate and 1, 2-bis-(4-carboxy-benzoyloxy)-ethane were non-intentional added substances. The detected substances were not in the GB 9685-2016 substance list and not allowed to be used. Under the TTC law, the detected substances were Cramer I substances, their exposure was significantly lower than the safety exposure threshold of 1.8 mg/person/day, low probability of adverse health effects to human health. |
| |
| Keywords: | |
|
| 点击此处可从《食品工业科技》浏览原始摘要信息 |
|
点击此处可从《食品工业科技》下载全文 |
|
