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EPR and optical spectra of Cu2 in dioptase
Authors:K M Reddy  A S Jacob  B J Reddy
Affiliation:  a Spectroscopic Laboratories, Dept. of Physics, S. V. University, Tirupati, India b Department of Physics, V. R. College, Nellore, India
Abstract:EPR and optical absorption studies of Dioptase have been carried out at room and low temperatures. The observed, absorption bands have been attributed to Cu2+ ion in C4V symmetry. From the g-values, the ground state of Cu2+ is found to be 2B1. The octahedral and tetragonal field parameters and the spin-orbit reduction parameters have been evaluated. The NIR and IR spectra have also been reported.
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