| 含邻苯二甲腈侧基的聚酰胺的合成与热行为 |
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| 引用本文： | 李黎,鲁东奎,郭乔,高帅,曾科,武迪蒙,朱俊,赵永超,申小华,杨刚. 含邻苯二甲腈侧基的聚酰胺的合成与热行为[J]. 高分子材料科学与工程, 2011, 0(10): 11-14 |
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| 作者姓名： | 李黎 鲁东奎 郭乔 高帅 曾科 武迪蒙 朱俊 赵永超 申小华 杨刚 |
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| 作者单位： | 四川大学高分子科学与工程学院高分子材料工程国家重点实验室; |
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| 基金项目： | 国家自然科学基金资助项目(21074077) |
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| 摘 要： | 合成了一种新型的含邻苯二甲腈基团的二胺4-（2,4-二氨基苯氧基）邻苯二甲腈（CNDA）,将它与苯甲酰氯和间苯二甲酰氯反应,分别合成了溶解性能良好的酰胺模型化合物（b-CNPA）和酰胺聚合物（m-CNPA）,并分别在265℃和275℃对它们进行热固化反应。热重分析（TGA）,差示扫描量热分析（DSC）和红外光谱（FT-...
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| 关 键 词： | 聚酰胺 邻苯二甲腈 固化反应 芳香族二胺 |
Synthesis and Thermal Behavior of Polyamides Containing Phthalonitrile Group on Their Pendant Groups |
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| Li Li,Dongkui Lu,Qiao Guo,Shuai Gao,Ke Zeng,Dimeng WuJun Zhu,Yongchao Zhao,Xiaohua Shen,Gang Yang. Synthesis and Thermal Behavior of Polyamides Containing Phthalonitrile Group on Their Pendant Groups[J]. Polymer Materials Science & Engineering, 2011, 0(10): 11-14 |
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| Authors: | Li Li Dongkui Lu Qiao Guo Shuai Gao Ke Zeng Dimeng WuJun Zhu Yongchao Zhao Xiaohua Shen Gang Yang |
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| Affiliation: | Li Li,Dongkui Lu,Qiao Guo,Shuai Gao,Ke Zeng,Dimeng WuJun Zhu,Yongchao Zhao,Xiaohua Shen,Gang Yang(College of Polymer Science and Engineering,State Key Laboratory of Polymer MaterialsEngineering,Sichuan University,Chengdu 610065,China) |
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| Abstract: | 4-(2,4-diaminophenoxy)phthalonitrile(CNDA) was synthesized and reacted with benzoyl chloride and m-phthaloyl chloride respectively,to get model compound(b-CNPA) and aromatic polyamide(m-CNPA),which have phthalonitrile on their pendant groups.The structures of them were verified by Fourier transform infrared spectrum(FT-IR),nuclear magnetic resonance spectrum(NMR) and their thermal behaviors were studied by thermogravimetric analysis(TGA),differential scanning calorimetry(DSC) and FT-IR.The results show that... |
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| Keywords: | polyamide phthalonitrile cure reaction aromatic diamine |
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